Equal Footing of Thermal Expansion and Electron-Phonon Interaction in the Temperature Dependence of Lead Halide Perovskite Band Gaps
Adrián Francisco-López, Bethan Charles, M. Isabel Alonso, Miquel Garriga, Mariano Campoy-Quiles, Mark T. Weller, Alejandro Goñi
J. Phys. Chem. Lett. 10, 2971−2977, 2019
DOI: 10.1021/acs.jpclett.9b00876
Figure: Sketch illustrating the contribution from thermal expansion (TE) and electron-phonon interaction (EP) to the temperature-induced renormalization of the perovskite band gap with temperature (data points).